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| The laser and Raman spectroscopy Raman understood the need for more intense light sources to amplify the effect and observation of the scattered light. The laser provided an even more intense source of light that not only could serve as a probe exploring the properties of the molecule but could also induce dramatically new effects. With the development of the Fourier transform (FT) technique and the application of computers for data handling, commercial FT-Raman spectrometers became available in the late 1980s, resulting in resurgence in the use of the original Raman Effect. The new Raman spectroscopy has been used to monitor manufacturing processes in the petrochemical and pharmaceutical industries. Illegal drugs captured at a crime scene can be analyzed rapidly without breaking the evidence seal on the plastic bag. Chemists can watch paint dry and understand what reactions are occurring as the paint hardens. Using a fiber-optic probe, they can analyze nuclear waste material from a safe distance. Photochemists and photobiologists are using laser Raman techniques to record the spectra of transient chemical species with lifetimes as small as 10-11 seconds. Surface-enhanced Raman spectroscopy is used for studying surfaces and reactions on surfaces. And, according to Kathy Kincade, Raman spectroscopy "has the ability to provide specific biochemical information that may foreshadow the onset of cancer and other life-threatening illnesses." In his 1928 talk in Bangalore, Raman concluded, "We are obviously only at the fringe of a fascinating new region of experimental research which promises to throw light on diverse problems relating to radiation and wave theory, X-ray optics, atomic and molecular spectra, fluorescence and scattering, thermodynamics, and chemistry. It all remains to be worked out." Seventy years later scientists are still actively working out the results and practical applications of Raman's deceptively simple experiment.
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The experiment |
The Raman Effect as the physicist's tool Copyright
©2006 American Chemical Society. All Rights Reserved. 1155 16th Street
NW, Washington DC 20036 |
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